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Updated: Jul 19, 2026

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
Published on: March 24, 2018
The intramolecular beta-fluorine...ammonium interaction in 4- and 8-membered rings
Natalie E J Gooseman1, David O'Hagan, Alexandra M Z Slawin
1School of Chemistry and Centre for Biomolecular Sciences, University of St Andrews, North Haugh, St Andrews, Fife, UK KY16 9ST.
Abstract:
The structures of 3-fluoroazetidinium hydrochloride and 3-fluoro-1,5-diazacyclooctane hydrobromide are explored both by X-ray diffraction analysis and DFT calculations, and the conformations of these molecules are shown to be significantly influenced by the through space C-F...N+ interaction.
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