Discrete copper(I) clusters with Cu6P6Se6 and Cu6P4Se6 cores
Robert P Davies1, M Giovanna Martinelli, Andrew J P White
1Department of Chemistry, Imperial College London, South Kensington, London, UK SW7 2AZ. r.davies@imperial.ac.uk
Chemical Communications (Cambridge, England)
|October 10, 2006
Summary
Chalcogenophosphinites react with copper(I) salts to form stable, multi-metallic copper-chalcogen clusters. These novel clusters exhibit unique and complex structural arrangements, advancing inorganic chemistry.
Area of Science:
- Inorganic Chemistry
- Materials Science
- Coordination Chemistry
Background:
- Chalcogenophosphinites are versatile ligands in coordination chemistry.
- Copper(I) metal salts are common precursors for cluster synthesis.
Purpose of the Study:
- To investigate the reactivity of chalcogenophosphinites with copper(I) metal salts.
- To synthesize and characterize novel multi-metallic copper-chalcogen based clusters.
Main Methods:
- Reaction of chalcogenophosphinites with copper(I) metal salts.
- Structural characterization of the resulting clusters using X-ray diffraction and spectroscopic techniques.
Main Results:
- Formation of highly stable, multi-metallic copper-chalcogen based clusters.
- Discovery of novel cluster topologies with unique structural features.
Conclusions:
- The reaction provides a viable route to complex copper-chalcogen clusters.
- These findings expand the scope of chalcogenophosphinite chemistry and copper cluster synthesis.
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