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Updated: Jul 19, 2026

Preparation and Reactivity of a Triphosphenium Bromide Salt: A Convenient and Stable Source of Phosphorus(I)
Published on: November 22, 2016
Self-assembly of square-planar halide complexes of phosphine-stabilised stibenium salts
J Wolfram Wielandt1, Nathan L Kilah, Anthony C Willis
1Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory 0200, Australia.
Abstract:
Chloride and bromide ions direct the self-assembly of supramolecular square-planar halide complexes in which four trimethylphosphine-stabilised diphenylstibenium ions surround the central halide ion in discrete centrosymmetrical structures of C(4h) symmetry.
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