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Synthesis of plakortone B and analogs
M F Semmelhack1, Richard J Hooley, Christina M Kraml
1Department of Chemistry, Frick Chemistry Laboratory, Princeton University, Princeton, New Jersey 08544, USA. mfshack@princeton.edu
Abstract:
[Structure: see text] Use of a palladium-mediated alkoxycarbonylation/lactonization process provides a variable route to analogs of the plakortones. Four different analogs, including natural plakortone B, have been synthesized via this route.
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