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Highly activated vinyl hydrogen in a significantly twisted styrene

Hajime Mori1, Takafumi Matsuo, Yasunori Yoshioka

  • 1School of Science and Technology, Kwansei Gakuin University, 2-1 Gakuen, Sanda, Hyogo 669-1337, Japan. hmori@wakayama-kg.go.jp

The Journal of Organic Chemistry
|November 18, 2006
PubMed
Summary

Researchers discovered vinyl hydrogens in twisted styrene derivatives are more reactive than benzylic hydrogens. This reactivity stems from unique orbital interactions in these sterically hindered molecules.

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