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Updated: Jul 18, 2026

Removal of Arsenic Using a Cationic Polymer Gel Impregnated with Iron Hydroxide
Published on: June 28, 2019
Arsenic removal by electrocoagulation using combined Al-Fe electrode system and characterization of products
Jewel A G Gomes1, Praveen Daida, Mehmet Kesmez
1Gill Chair of Chemistry and Chemical Engineering, Lamar University, P.O. Box 10022, Beaumont, TX 77710, USA.
Abstract:
Combination of electrodes, such as aluminum and iron in a single electrochemical cell provide an alternative method for removal of arsenic from water by electrocoagulation. The removal process has been studied with a wide range of arsenic concentration (1-1000 ppm) at different pH (4-10). Analysis of the electrochemically generated by-products by XRD, XPS, SEM/EDAX, FT-IR, and Mössbauer Spectroscopy revealed the expected crystalline iron oxides (magnetite (Fe3O4), lepidocrocite (FeO(OH)), iron oxide (FeO)) and aluminum oxides (bayerite (Al(OH)3), diaspore (AlO(OH)), mansfieldite (AlAsO(4).2(H2O)), as well as some interaction between the two phases. The amorphous or very fine particular phase was also found in the floc. The substitution of Fe3+ ions by Al3+ ions in the solid surface has been observed, indicating an alternative removal mechanism of arsenic in these metal hydroxides and oxyhydroxides by providing larger surface area for arsenic adsorption via retarding the crystalline formation of iron oxides.
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