Solid mining residues from ni extraction applied as nutrients supplier to anaerobic process: optimal dose approach...

The use of solid mining residues (Cola) which contain a certain amount of Ni, Fe and Co, to stimulate anaerobic processes was evaluated. The effect over methane production and chemical oxygen demand (COD) removal efficiency was analysed. The studies were carried out in discontinuous reactors at lab scale under mesophilic conditions until exhausted. 0, 3, 5 and 7 mg Cola l(-1) doses were applied to synthetic wastewater. Volatile fatty acids (VFA) and sucrose were used as substrate, sulphur and nitrogen concentration, being the noise variable. Cola addition at dose around 5 mg I(-1), turned out to be stimulating for the anaerobic process. It was the factor that most influenced on methane production rate together with VFA and high content of volatile suspended solids. In the case of methane yield, pH was the control factor of strongest influence. Higher values of COD removal efficiency were obtained when the reactors were operated with sucrose at relatively low pH and at the smallest concentration of nitrogen and sulphur. Solid residues dose and the type of substrate were the factors that had most influence on COD removal efficiency.