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Uniform NH4TiOF3 mesocrystals prepared by an ambient temperature self-assembly process and their topotaxial

Lei Zhou1, David Smyth Boyle, Paul O'Brien

  • 1School of Chemistry and Manchester Materials Science Centre, University of Manchester, Oxford Road, Manchester, UKM13 9PL.

Chemical Communications (Cambridge, England)
|December 21, 2006
PubMed

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Ionic Crystal Structures

Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...