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Synthesis and Catalytic Performance of Gold Intercalated in the Walls of Mesoporous Silica
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Stereoselective stilbene epoxidation over supported gold-based catalysts

Pascal Lignier1, Franck Morfin, Stéphane Mangematin

  • 1Institut de Recherches sur la Catalyse (CNRS), 2 avenue Albert Einstein, 69626 Villeurbanne Cedex, France.

Chemical Communications (Cambridge, England)
|December 21, 2006
PubMed
Summary

The gold catalyst Au/TiO(2) efficiently drives stereoselective epoxidation of trans-stilbene. It utilizes a radical chain reaction involving methylcyclohexane and tert-butyl hydroperoxide (TBHP) to activate molecular oxygen.

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