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Atropisomers of meso-conjugated uracyl porphyrin derivatives and their assembling structures
Satoshi Arai1, Daisuke Niwa, Hiroyuki Nishide
1Department of Applied Chemistry, Waseda University, 3-4-1 Okubo, Shinjuku-ku, Tokyo 169-8555, Japan.
Abstract:
[reaction: see text] We have synthesized a 5,15 meso-substituted methyluracyl porphyrin derivative bearing 6-methyluracyl units directly at the meso positions. The atropisomerization was regulated by steric replusion between the methyl substituents. When the atropisomers were mixed with alkylated melamine as a complementary hydrogen-bonding unit, the hydrogen-bonded assemblies were analyzed by diffusion-ordered spectroscopy (DOSY) in solution, which clarified that the alphabeta isomer formed a face-to-face dimer, whereas the alphabeta isomer took a zigzag structure.
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