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Photo-Fries reaction in water made selective with a capsule

Lakshmi S Kaanumalle1, Corinne L D Gibb, Bruce C Gibb

  • 1Department of Chemistry, University of Miami, Coral Gables, Florida 33155, USA.

Organic & Biomolecular Chemistry
|January 6, 2007
PubMed

Abstract:

The water soluble capsule formed by a deep cavity cavitand with eight carboxylic acid groups controls product distribution during photo-Fries rearrangement of naphthyl esters in water by restricting the mobility of primary singlet radical pair.

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