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Published on: June 13, 2022
Further eudesmane derivatives from verbesina species
J Jakupovic1, E Ellmauerer, Y Jia
1Institute for Organic Chemistry, Technical University of Berlin, Straße des 17. Juni 135, D-1000 Berlin 12, Germany.
Abstract:
The aerial parts of VERBESINA PERSICIFOLIA DC afforded a new eudesmane derivative in addition to known compounds. The roots of V. SUBCORDATA gave also new eudesmane cinnamates in addition to several known ones as well as a 5alpha-hydroxybicyclogermacra-1 (10) E, 4 (15)-diene. A reinvestigation of V. VIRGINICA L. gave two new ( Z)-configurated coumarates. Furthermore the structures of some sesquiterpenes are revised. The structures were elucidated by highfield NMR spectroscopy and a few chemical reactions.
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