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Preparation of Highly Porous Coordination Polymer Coatings on Macroporous Polymer Monoliths for Enhanced Enrichment of Phosphopeptides
Published on: July 14, 2015
Rationally designed micropores within a metal-organic framework for selective sorption of gas molecules
Banglin Chen1, Shengqian Ma, Fatima Zapata
1Department of Chemistry, University of Texas-Pan American, Edinburg, TX 78541-2999, USA. banglin@utpa.edu
Inorganic Chemistry
|February 13, 2007
Abstract:
A microporous metal-organic framework, MOF, Cu(FMA)(4,4'-Bpe)0.5 (3a, FMA = fumarate; 4,4'-Bpe = 4,4'-Bpe = trans-bis(4-pyridyl)ethylene) was rationally designed from a primitive cubic net whose pores are tuned by double framework interpenetration. With pore cavities of about 3.6 A, which are interconnected by pore windows of 2.0 x 3.2 A, 3a shows highly selective sorption behaviors of gas molecules.
