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Computational study about through-bond and through-space interactions in [2.2]cyclophanes.

Giovanni F Caramori1, Sérgio E Galembeck

  • 1Departamento de Química, Faculdade de Filosofia, Ciencias e Letras de Ribeirão Preto, Universidade de São Paulo, 14040-901 Ribeirão Preto-SP, Brazil.

The Journal of Physical Chemistry. A
|February 14, 2007
PubMed
Summary

[2.2]Cyclophane isomers exhibit through-bond interactions, while [2.2]metacyclophane conformers show stabilizing through-space interactions. Other isomers display repulsive interactions, and bridge positioning impacts atomic properties.

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