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A controlled approach to well-defined oligothiophenes via oxidatively induced reductive elimination of stable Pt(II)

Fan Zhang1, Peter Bäuerle

  • 1Institute of Organic Chemistry II and Advanced Materials, University of Ulm, Albert-Einstein-Allee 11, D-89081 Ulm, Germany.

Journal of the American Chemical Society
|February 24, 2007
PubMed
Abstract

No abstract available in PubMed .

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The radical dimerization of ketones or aldehydes gives vicinal diols through a pinacol coupling reaction. However, the behavior of titanium metals used for the reaction as a source of electrons is unusual. When the reaction is carried out in the presence of titanium, diols can be isolated at low temperatures. Else titanium further reacts with diols, forming alkenes through the McMurry reaction.