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Ligand effects on Ni(II)-catalysed alkane-hydroxylation with m-CPBA

Takayuki Nagataki1, Kenta Ishii, Yoshimitsu Tachi

  • 1Department of Chemistry, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan. shinobu@sci.osaka-cu.ac.jp

Dalton Transactions (Cambridge, England : 2003)
|March 7, 2007
PubMed
Summary

New nickel(II) complexes with pyridylalkylamine ligands were synthesized and tested for cyclohexane oxidation. Pyridylmethylamine ligands improved turnover, while pyridylethylamine ligands enhanced selectivity, with nitrate co-ligands causing initial reaction delays.

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