Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

New copper and silver trimethylsilylchalcogenolates.

Aneta Borecki1, John F Corrigan

  • 1Department of Chemistry, The University of Western Ontario, London, Ontario N6A 5B7, Canada.

Inorganic Chemistry
|March 14, 2007
PubMed
Summary
This summary is machine-generated.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Dual Cluster-Surface Click Chemistries on Silver Nanoclusters.

Small science·2026
Same author

Ag<sub>20</sub> Nanoclusters with Surface Azides as an Easily Functionalized Platform for Diverse Chemical Applications.

Small (Weinheim an der Bergstrasse, Germany)·2024
Same author

Self-Immolative Hydrogels with Stimulus-Mediated On-Off Degradation.

Biomacromolecules·2023
Same author

Controlling the Structure, Properties and Surface Reactivity of Clickable Azide-Functionalized Au<sub>25</sub> (SR)<sub>18</sub> Nanocluster Platforms Through Regioisomeric Ligand Modifications.

Angewandte Chemie (International ed. in English)·2022
Same author

Self-immolative polyplexes for DNA delivery.

Biomaterials science·2022
Same author

Correction to "Thermoresponsive and Covalently Cross-Linkable Hydrogels for Intra-Articular Drug Delivery".

ACS applied bio materials·2022

New copper and silver trimethylsilylchalcogenolate complexes were synthesized. These compounds exhibit thermal instability but structural characterization reveals key coordination details and reactivity pathways.

Area of Science:

  • Organometallic Chemistry
  • Coordination Chemistry
  • Materials Science

Background:

  • Trimethylsilylchalcogenolates offer unique ligand properties.
  • Copper and silver complexes are vital in catalysis and materials.

Purpose of the Study:

  • To synthesize and characterize novel copper and silver trimethylsilylchalcogenolate complexes.
  • To investigate the structural and reactivity aspects of these organometallic compounds.

Main Methods:

  • High-yield synthesis of chalcogenolate complexes.
  • Low-temperature single-crystal X-ray diffraction for structural analysis.
  • Protonolysis and heterometallic cluster formation reactions.

Main Results:

Related Experiment Videos

  • Successful synthesis of copper and silver trimethylsilylchalcogenolates.
  • X-ray analysis confirmed terminal chalcogen coordination and tetrahedral metal centers.
  • Demonstrated thermal instability and reactivity, including selenol complex formation and heterometallic cluster synthesis.

    • Conclusions:

    • The synthesized chalcogenolate complexes provide insights into metal-chalcogen bonding.
    • Reactivity studies highlight pathways for generating new organometallic structures.
    • The findings contribute to the understanding of copper and silver chalcogenide chemistry.