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Updated: Jul 16, 2026

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
09:35

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

Synthesis of densely functionalised arenes using [2 + 2 + 2] cycloaddition reactions

Jonathan Clayden1, Wesley J Moran

  • 1School of Chemistry, The University of Manchester, Oxford Road, Manchester, UK. clayden@man.ac.uk

Organic & Biomolecular Chemistry
|March 23, 2007
PubMed
Summary

Rhodium(I)-catalyzed cycloaddition synthesizes sterically hindered aryl ethers and diarylmethanes from simple alkynes. The resulting diarylmethanes did not exhibit rotational restriction in NMR spectra.

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