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Updated: Jul 16, 2026

Gas Chromatography-Mass Spectrometry Paired with Total Vaporization Solid-Phase Microextraction as a Forensic Tool
Published on: May 25, 2021
Characterization of solid-phase microextraction and gas chromatography for the analysis of gasoline tracers in
Diana Ceballos1, Barbara Zielinska, Eric Fujita
1University of Washington, Seattle, WA, USA.
Abstract:
Gasoline tracers were collected on solid-phase microextraction (SPME) fibers and analyzed by capillary gas chromatography with photoionization detector (GC/PID). This was part of a larger study to quantify personal exposure to motor vehicle gasoline evaporative and combustive emissions in high-end exposure microenvironments (MEs). The SPME fiber selected for this application was a 75-microm carboxen/polydimethylsiloxane. Sequential 10-min samples were collected for measurement of benzene, toluene, ethylbenzene, and ortho-, meta-, and para-xylene in different MEs in Atlanta, GA, in summer 2002 and Reno, NV, in spring 2003. Field calibrations were performed with certified gas standards in 1-L Tedlar bags for varying concentrations and exposure times. SPME detection limits were approximately 0.2 ppbv with a precision of 3-17% and accuracy of 30%. A dynamic system was designed for temperature and relative humidity calibrations, with corrections for the effects of these variables performed when necessary. SPME data compared satisfactorily with integrated canister samples, continuous PID, and field portable mass spectrometer data.
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