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Updated: Jul 16, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Synthesis of nitrogen-containing compounds using chromium Fischer carbene complexes
Hirotaka Kagoshima1, Kohei Fuchibe, Takahiko Akiyama
1Department of Chemistry, Faculty of Science, Gakushuin University, 1-5-1 Mejiro, Tokyo 171-8588, Japan.
Abstract:
Synthetic utility of the Fischer-type carbene complexes of chromium for the preparation of nitrogen-containing compounds is demonstrated. Alkoxy carbene complexes reacted with imines to give (optically active) 3-pyrrolines and beta-methoxy allylic amine derivatives in good yields. The amino carbene complexes reacted with alpha,beta-unsaturated aldehydes to give substituted pyrroles in good yields.
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