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Published on: January 23, 2013
Polybenzoxazine as a mold-release agent for nanoimprint lithography
Chih-Feng Wang1, Shih-Feng Chiou, Fu-Hsiang Ko
1Department of Materials Science and Engineering, I-Shou University, 84008 Kaohsiung, Taiwan.
Langmuir : the ACS Journal of Surfaces and Colloids
|April 27, 2007
Summary
Eliminating resist sticking in nanoimprint lithography is crucial. Polybenzoxazine offers an efficient, cost-effective mold-release agent for silicon molds, simplifying processing and avoiding side reactions.
Area of Science:
- Materials Science
- Nanotechnology
- Surface Chemistry
Background:
- Nanoimprint lithography (NIL) faces challenges with mold-release, specifically resist sticking.
- Current mold-release agents, like fluorinated alkyl silanes, involve complex, costly application processes.
- These agents can also lead to undesirable side reactions.
Purpose of the Study:
- To identify a more efficient and cost-effective mold-release agent for silicon molds in NIL.
- To overcome the limitations of existing mold-release strategies.
- To investigate polybenzoxazine as a novel solution for demolding issues.
Main Methods:
- Investigated polybenzoxazine, a low surface free energy material.
- Evaluated its performance as a mold-release agent on silicon molds.
- Assessed processing ease, cost-effectiveness, and potential side reactions.
Main Results:
- Polybenzoxazine demonstrated efficient mold-release properties for silicon molds.
- The material is easier to process compared to traditional agents.
- It offers a cost-effective solution with no observed side reactions.
Conclusions:
- Polybenzoxazine is a highly effective and practical mold-release agent for nanoimprint lithography.
- It presents a significant improvement over conventional methods, reducing complexity and cost.
- This material facilitates smoother NIL processes by preventing resist sticking.

