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Related Concept Videos

Inductively Coupled Plasma Atomic Emission Spectroscopy: Instrumentation01:26

Inductively Coupled Plasma Atomic Emission Spectroscopy: Instrumentation

Inductively coupled plasma (ICP) is the common plasma source used in atomic emission spectroscopy (AES), a technique that detects and analyzes various elements in a sample. This method is often called inductively coupled plasma atomic emission spectroscopy (ICP-AES).
There are three main types of inductively coupled plasma atomic emission spectroscopy  (ICP-AES) instruments: sequential, simultaneous multichannel, and Fourier transform instruments, with the latter being less commonly used.
Atomic Absorption Spectroscopy: Radiation and Light Sources01:13

Atomic Absorption Spectroscopy: Radiation and Light Sources

Atomic absorption spectroscopy (AAS) relies on the Beer-Lambert law, which requires that the radiation source emits a narrow range of wavelengths to match the absorption characteristics of the analyte atom. The primary criteria for choosing an appropriate radiation source in AAS is to provide a precise and intense emission at specific wavelengths that will allow accurate detection of the analyte.
Two common narrow-range 'line' sources used in AAS are hollow-cathode lamps (HCLs) and...
Infrared (IR) Spectroscopy: Overview01:09

Infrared (IR) Spectroscopy: Overview

When electromagnetic radiation passes through a material, atoms or molecules transition from a lower to a higher energy state by absorbing radiation corresponding to the energy difference between the two states. The absorption of infrared (IR) radiation causes transitions between vibrational energy levels in a molecule. Therefore, IR spectroscopy is a useful analytical tool for determining the molecular structure of molecules.
Different compounds display unique properties due to their...
Molecular Spectroscopy: Absorption and Emission01:14

Molecular Spectroscopy: Absorption and Emission

Molecules possess discrete energy levels called quantum states. Unlike atoms, which have simpler energy levels, molecules possess additional rotational and vibrational energy levels. Each energy level is separated by an energy gap, with the gaps between adjacent electronic, vibrational, and rotational levels varying significantly. The three types of energy levels in a diatomic molecule are shown in Figure 1.
Atomic Absorption Spectroscopy: Instrumentation01:22

Atomic Absorption Spectroscopy: Instrumentation

An atomic absorption spectrophotometer (AAS) comprises several components: a radiation source, an atomizer, a monochromator, and a detector. The radiation source can be a hollow-cathode lamp (HCL) or an electrodeless-discharge lamp (EDL), both of which provide a narrow emission line of the required wavelength. However, some instruments use continuum sources and high-resolution monochromators to achieve a narrow range of radiation.
The atomizer used in AAS can be either a flame atomizer or an...
Atomic Spectroscopy: Absorption, Emission, and Fluorescence01:23

Atomic Spectroscopy: Absorption, Emission, and Fluorescence

Atomic spectroscopy is a vital tool in elemental analysis, both qualitatively and quantitatively. It can be broadly divided into optical spectroscopy, mass spectroscopy, and X-ray spectroscopy methods. The optical spectroscopic methods are atomic absorption spectroscopy (AAS), atomic emission spectroscopy (AES), and atomic fluorescence spectroscopy (AFS). The first step in all three methods is atomization, where the solid, liquid, or solution-phase samples are converted into gas-phase atoms and...

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Updated: Jul 14, 2026

Fabrication And Characterization Of Photonic Crystal Slow Light Waveguides And Cavities
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Published on: November 30, 2012

Fourier-transform cavity-enhanced absorption spectroscopy using an incoherent broadband light source.

Albert A Ruth1, Johannes Orphal, Sven E Fiedler

  • 1Department of Physics, National University of Ireland, University College Cork, Cork, Ireland. a.ruth@ucc.ie

Applied Optics
|May 22, 2007
PubMed
Summary

Cavity-enhanced absorption spectroscopy significantly boosts Fourier-transform spectrometer sensitivity for measuring oxygen and water vapor. This technique enhances path length by 200x, improving signal-to-noise for gas analysis.

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Area of Science:

  • Spectroscopy
  • Atmospheric Chemistry
  • Physical Chemistry

Background:

  • Fourier-transform spectroscopy (FTS) is a powerful tool for gas analysis.
  • Measuring weak absorption features, like the spin-forbidden B-band of oxygen, requires high sensitivity.
  • Traditional FTS methods can be limited by path length and signal-to-noise ratios.

Purpose of the Study:

  • To enhance the sensitivity of Fourier-transform spectroscopy for gas-phase measurements.
  • To measure weak absorption transitions of gaseous oxygen and water vapor.
  • To evaluate the effectiveness of cavity-enhanced absorption spectroscopy (CEAS) for this purpose.

Main Methods:

  • Utilized a cavity-enhanced absorption setup with an incoherent broadband light source.
  • Combined CEAS with a Fourier-transform spectrometer.
  • Operated at room temperature in ambient air to measure absorption spectra around 688 nm.

Main Results:

  • Achieved a path-length enhancement factor of 200 compared to single-pass measurements.
  • Reported an approximate 6-fold improvement in the signal-to-noise ratio.
  • Successfully measured the spin-forbidden B-band of oxygen and weak water vapor transitions.

Conclusions:

  • Cavity-enhanced absorption spectroscopy significantly improves FTS sensitivity.
  • The method allows for sensitive gas measurements with a small sample volume.
  • This technique offers practical advantages for atmospheric and chemical analysis.