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Updated: Jul 14, 2026

Thermal Scanning Conductometry (TSC) as a General Method for Studying and Controlling the Phase Behavior of Conductive Physical Gels
Published on: January 23, 2018
The chemical effects of molecular sol-gel entrapment
Mario Pagliaro1, Rosaria Ciriminna, Giovanni Palmisano
1Istituto per lo Studio dei Materiali Nanostrutturati, Cnr, via U. La Malfa 153, 90146 Palermo, Italy. mario.pagliaro@ismn.cnr.it
Abstract:
Chemical conversions within the cages of doped sol-gel porous oxides take place with unique advantages over reactions in solution as the glassy matrix has tremendous effects on the reactivity of the entrapped molecules. The chemical properties of sol-gel materials can be tailored in an immense range of values and chemists are increasingly achieving control on reactions taking place within these matrices, including crucially important photovoltaics. Highlighting recent major advancements, we show in this tutorial review how this is actually taking place.
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