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Updated: Jul 14, 2026

Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst
Published on: April 22, 2016
Amplified spontaneous emission in polymer films doped with a perylenediimide derivative
Eva M Calzado1, José M Villalvilla, Pedro G Boj
1Departmento de Física Aplicada and Instituto Universitario de Materiales de Alicante, Universidad de Alicante, 03080-Alicante, Spain.
Abstract:
The presence of amplified spontaneous emission (ASE) by optical pump in polystyrene films doped with N,N'-di(10-nonadecyl)perylene-3,4:9,10-tetracarboxylic diimide (PDI-N) in a range of PDI-N concentrations between 0.25 and 5 wt. % is reported. Gain coefficients up to 10 cm(-1), at a pump intensity of 74 kW/cm2, were obtained. The lowest thresholds (approximately 15 kW/cm2) and largest photostabilities measured at 50% (approximately 50 min, i.e., 30,000 pump pulses) were obtained for concentrations up to 1 wt. %. The observation of an increase in the ASE threshold and a decrease in the photostability for larger concentrations is attributed to the presence of aggregated species.
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