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Novel ebselen-porphyrin conjugates: synthesis and nucleic acid interaction study

Zhi Xue1, An-Xin Hou, Daniel Wei-Jing Kwong

  • 1Department of Chemistry, Wuhan University, Wuhan 430072, PR China.

Bioorganic & Medicinal Chemistry Letters
|June 9, 2007
PubMed

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Phase II biotransformations are detoxification mechanisms that conjugate xenobiotics with endogenous substances, neutralizing their toxicity.
A key example involves the conjugation of cyanide ions, which impair cellular respiration and alter hemoglobin into non-oxygen-carrying cyanmethemoglobin. To neutralize this threat, a sulfur atom from thiosulphate is transferred to the cyanide ion, catalyzed by the enzyme rhodanese, resulting in an inactive compound called thiocyanate. The production of...