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Solvation, solute rotation and vibration relaxation, and electron-transfer reactions in room-temperature ionic
Youngseon Shim1, Daun Jeong, Swati Manjari
1Department of Chemistry, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213, USA.
Abstract:
A brief account of recent simulation and theoretical model studies of various solution-phase processes in room-temperature ionic liquids is given. These include structure and dynamics of equilibrium and nonequilibrium solvation, solute rotation and vibrational energy relaxation, and free energetics and dynamics of unimolecular electron-transfer reactions. Special attention is paid to both the aspects shared by and the contrasts with polar solvents under normal conditions. A brief comparison with available experiments is also made.
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