Related Experiment Video
Updated: Jul 12, 2026
![Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F55858.jpg&w=3840&q=50)
10:01
Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase
Published on: December 4, 2017
Hydrogen Sulfide on IO: Evidence from Telescopic and Laboratory Infrared Spectra.
Summary
Hydrogen sulfide (H2S) frost has been detected on Jupiter's moon Io. This transient H2S frost influences Io's surface brightness and atmospheric composition.
Area of Science:
- Planetary Science
- Astrobiology
- Spectroscopy
Background:
- Jupiter's moon Io exhibits complex geological activity driven by tidal heating.
- The surface composition of Io is primarily dominated by sulfur dioxide (SO2) frost.
- Previous observations have hinted at the presence of other volatile compounds on Io's surface.
Purpose of the Study:
- To investigate the presence and characteristics of hydrogen sulfide (H2S) on Io's surface.
- To understand the implications of H2S frost for Io's atmospheric composition and surface properties.
- To analyze spectral data for unique signatures indicative of H2S frost.
Main Methods:
- Utilized ground-based telescopic observations to obtain infrared spectra of Io.
- Analyzed spectral data for an absorption band at 3.915 micrometers, characteristic of H2S frost.
- Correlated the presence and intensity of the H2S band with Io's orbital longitude and illumination conditions.
Main Results:
- Detected an infrared band at 3.915 µm, attributed to H2S frost, either pure or mixed with SO2 frost.
- Observed temporal variations in the H2S band's occurrence and intensity, suggesting transient surface deposits.
- The H2S band was detected at various longitudes, indicating widespread, though sparse and variable, distribution.
- H2S frost presence correlates with increased surface brightness in ultraviolet and visible wavelengths.
Conclusions:
- Provides direct evidence for hydrogen sulfide (H2S) frost on Io's surface.
- H2S frost is a transient component of Io's surface, varying in abundance and distribution.
- The presence of H2S significantly impacts Io's spectral properties and surface appearance.
More Related Videos
Related Concept Videos
IR Spectrum Peak Broadening: Hydrogen Bonding
The vibrational frequency of a bond is directly proportional to its bond strength. As a result, stronger bonds vibrate at higher frequencies, while weaker bonds vibrate at lower frequencies. The stretching vibration of the strong O–H bond in alcohols and phenols (very dilute solution or gas phase) appears as a sharp peak at 3600–3650 cm−1.
However, the extent of hydrogen bonding influences the observed stretching frequency and band broadening. Intermolecular or intramolecular hydrogen bonding...
However, the extent of hydrogen bonding influences the observed stretching frequency and band broadening. Intermolecular or intramolecular hydrogen bonding...
Infrared (IR) Spectroscopy: Overview
When electromagnetic radiation passes through a material, atoms or molecules transition from a lower to a higher energy state by absorbing radiation corresponding to the energy difference between the two states. The absorption of infrared (IR) radiation causes transitions between vibrational energy levels in a molecule. Therefore, IR spectroscopy is a useful analytical tool for determining the molecular structure of molecules.
Different compounds display unique properties due to their...
Different compounds display unique properties due to their...
Emission Spectra
When solids, liquids, or condensed gases are heated sufficiently, they radiate some of the excess energy as light. Photons produced in this manner have a range of energies, and thereby produce a continuous spectrum in which an unbroken series of wavelengths is present.
IR Spectrum
When infrared (IR) radiation passes through a molecule, the bonds stretch or bend by absorbing the radiation. This absorption creates the molecule's absorption spectrum, which is the plot of its percentage transmittance versus wavenumber.
Transmittance is defined as the ratio of the radiant power passing through a sample to that from the radiation's source. Multiplying the transmittance by 100 gives the percent transmittance (%T), which varies between 100% (no absorption) and 0% (complete...
Transmittance is defined as the ratio of the radiant power passing through a sample to that from the radiation's source. Multiplying the transmittance by 100 gives the percent transmittance (%T), which varies between 100% (no absorption) and 0% (complete...
Preparation and Reactions of Sulfides
Sulfides are the sulfur analog of ethers, just as thiols are the sulfur analog of alcohol. Like ethers, sulfides also consist of two hydrocarbon groups bonded to the central sulfur atom. Depending upon the type of groups present, sulfides can be symmetrical or asymmetrical. Symmetrical sulfides can be prepared via an SN2 reaction between 2 equivalents of an alkyl halide and one equivalent of sodium sulfide.
IR Absorption Frequency: Hybridization
Hydrocarbons such as alkanes, alkenes, and alkynes show characteristic C–H stretching absorption bands. These IR stretching frequencies depend on the hybridization of the involved carbon atom and can be explained in terms of the s character of each hybridized atomic orbital.
Among the sp, sp2, and sp3 hybridized orbitals, sp orbitals have the maximum s character (50%). Consequently, the electrons are held more closely to the nucleus, resulting in stronger and shorter C–H bonds that stretch at a...
Among the sp, sp2, and sp3 hybridized orbitals, sp orbitals have the maximum s character (50%). Consequently, the electrons are held more closely to the nucleus, resulting in stronger and shorter C–H bonds that stretch at a...

