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Anionic Polymerization of an Amphiphilic Copolymer for Preparation of Block Copolymer Micelles Stabilized by π-π Stacking Interactions
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Pressure-induced reentrant micellization of amphiphilic block copolymers in dilute aqueous solutions

Noboru Osaka1, Sho Miyazaki, Satoshi Okabe

  • 1Neutron Science Laboratory, Institute for Solid State Physics, The University of Tokyo, Tokai, Ibaraki 319-1106, Japan.

The Journal of Chemical Physics
|September 11, 2007
PubMed

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Micelle formation is an intricate process that hinges on the properties of amphiphilic or amphipathic molecules and the conditions of the system in which they are found. Amphiphilic molecules, which have both hydrophilic (water-attracting) and hydrophobic (water-repelling) parts, play a critical role in this process.In aqueous environments, these molecules arrange themselves such that their hydrophilic heads are turned towards the water phase, while their hydrophobic tails are oriented away...