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Synthesis and Catalytic Performance of Gold Intercalated in the Walls of Mesoporous Silica
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Published on: July 9, 2015

Gold nanoparticles and gold(III) complexes as general and selective hydrosilylation catalysts

Avelino Corma1, Camino González-Arellano, Marta Iglesias

  • 1Instituto de Tecnología Química, UPV-CSIC, Avda. de los Naranjos s/n, 46022 Valencia, Spain. acorma@itq.upv.es

Angewandte Chemie (International Ed. in English)
|September 12, 2007
PubMed
Abstract

No abstract available in PubMed .

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Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...

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