Emission of Au nanoparticles with and without rhodamine 6G dye

We have observed Stokes and anti-Stokes emission of Au nanoparticles suspended in methanol and rhodamine 6G dye solution. Photoluminescence of Au nanoparticles is a three-step process involving single-photon or three-photon excitation of electron-hole pairs, relaxation of excited electrons and holes, and emission from electron-hole recombination, possibly enhanced by surface plasmons. In the presence of dye, the excitation of anti-Stokes emission of gold involves two-photon absorption in rhodamine 6G molecules followed by the energy transfer to Au nanoparticles with simultaneous absorption of one pumping photon by Au. This mechanism significantly enhances anti-Stokes emission of gold nanoparticles in the presence of dye.