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Preparation of carbohydrate-oligonucleotide conjugates using the squarate spacer

Hongbin Yan1, Aimé López Aguilar, Yuyan Zhao

  • 1Department of Chemistry, Brock University, St. Catharines, Ont., Canada L2S 3A1. tyan@brocku.ca

Bioorganic & Medicinal Chemistry Letters
|October 16, 2007
PubMed

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Protein glycosylation starts in the ER lumen and continues in the Golgi apparatus. Glycosyltransferases catalyze the addition of sugar molecules or glycosylation of proteins. Usually, these enzymes add sugars to the hydroxyl groups of selected serine or threonine residues to form O-linked glycans or the amino groups of asparagine residues to form N-linked glycans. Different positions on the same polypeptide chain can contain differently linked glycans.
Multiple sugar molecules that may or may...