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Updated: Jul 10, 2026
![[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
[Bis(3,5-dimethylpyrazol-1-yl-kappaN2)dithioacetato-kappaS](triphenylphosphine-kappaP)copper(I)
Lei Lei Liu1, Xiao Yan Tang, Hong Xi Li
1Key Laboratory of Organic Synthesis of Jiangsu Province, School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215123, Jiangsu, People's Republic of China.
Abstract:
In the title compound, [Cu(C(12)H(15)N(4)S(2))(C(18)H(15)P)], the copper(I) center is tetrahedrally coordinated by one S atom and two N atoms from one bis(3,5-dimethylpyrazol-1-yl)dithioacetate ligand and one P atom from a triphenylphosphine ligand. In the crystal structure, adjacent pyrazole rings are involved in weak pi-pi interactions, thereby forming a one-dimensional zigzag chain running along the b axis.
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