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O-cresol Concentration Online Measurement Based On Near Infrared Spectroscopy Via Partial Least Square Regression
Published on: November 8, 2019
[Influence of sample loading and test conditions on NIR veracity and study of analysis error source]
Jun-Hui Li1, Xi-Yun Qin, Wen-Juan Zhang
1College of Information and Electrical Engineering, China Agricultural University, Beijing 100094, China. caunir@cau.edu.cn
This study investigated how sample test conditions affect Near-Infrared (NIR) analysis accuracy in Yunnan flue-cured tobacco. Optimizing sample preparation and controlling test conditions are crucial for reliable NIR spectroscopy results.
Area of Science:
- Analytical Chemistry
- Spectroscopy
Context:
- Near-Infrared (NIR) spectroscopy is a valuable tool for analyzing agricultural products.
- Variability in sample test conditions can significantly impact the accuracy of NIR analysis.
- Developing robust analytical methods requires understanding and mitigating sources of error.
Purpose:
- To investigate the influence of sample test conditions on the accuracy of Near-Infrared (NIR) spectroscopy.
- To quantify the contributions of different error sources (repetition, re-loading, sample tightness) in a homemade diffuse NIR instrument.
- To provide theoretical data for improving homemade NIR instruments and analytical methodologies.
Summary:
- A homemade grating diffuse NIR instrument was used to analyze Yunnan flue-cured tobacco.
- Model self-emendation was employed to deduce analysis errors.
- Instrument signal-to-noise ratio (S/N) contributed to repetition (50%), re-loading (30%), and sample tightness (20%) errors.
- Sample preparation (depressing sample) can reduce tightness errors.
- Variations in test conditions introduced more error than repetition errors.
Impact:
- Provides theoretical insights into the impact of sample test conditions on NIR analysis veracity.
- Offers foundational data for the enhancement of homemade NIR instrumentation.
- Presents a novel approach for addressing errors in NIR spectroscopic analysis.
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