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Radially diblock nanotube: site-selective functionalization of a tubularly assembled hexabenzocoronene

Justin L Mynar1, Takuya Yamamoto, Atsuko Kosaka

  • 1ERATO-SORST Nanospace Project, Japan Science and Technology Agency, National Museum of Emerging Science and Innovation, 2-41 Aomi, Koto-ku, Tokyo 135-0064, Japan.

Journal of the American Chemical Society
|January 12, 2008
PubMed
Abstract

No abstract available in PubMed .

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Unlike the easy catalytic hydrogenation of an alkene double bond, hydrogenation of a benzene double bond under similar reaction conditions does not take place easily. For example, in the reduction of stilbene, the benzene ring remains unaffected while the alkene bond gets reduced. Hydrogenation of an alkene double bond is exothermic and a favorable process. In contrast, to hydrogenate the first unsaturated bond of benzene, an energy input is needed; that is, the process is endothermic. This is...

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