Nuclear relaxation effects in Davies ENDOR variants

John J L Morton1, Nicholas S Lees, Brian M Hoffman

  • 1Department of Materials, Oxford University, Oxford OX1 3PH, UK. john.morton@sjc.ox.ac.uk <john.morton@sjc.ox.ac.uk>

Summary

Saturated Pulsed ENDOR distinguishes electron-nuclear double resonance (ENDOR) peaks without an initial microwave pulse. This technique optimizes signal sensitivity and can determine hyperfine coupling constant signs, outperforming Davies ENDOR.

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