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Direct Imaging of Laser-driven Ultrafast Molecular Rotation
Published on: February 4, 2017
Raman Frequency Shifting in a CH(4):H(2):Ar mixture pumped by the fourth harmonic of a Nd:YAG Laser
Applied Optics
|February 28, 2008
Abstract:
Mixtures of methane, hydrogen, and argon (CH(4):H(2):Ar) were studied as UV Raman shifters for ozone differential absorption lidar application. They have higher photochemical stability than pure CH(4) and the capability to produce, with high enough efficiency, either first CH(4) Stokes or, simultaneously, CH(4) and H(2) first Stokes with equal energies. These mixtures can be used as an inexpensive replacement for D(2) or a more stable substitute for pure CH(4) in single-pass high-power Raman shifters.
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A conventional Raman spectrophotometer includes a laser source, a sample holding system, a wavelength selector, and a detector.
The monochromatic laser source, typically using visible or near-infrared radiation, generates a highly focused beam of light. This light interacts with the molecules of the sample, scattering some of the light. Liquid and gaseous samples are usually tested in ordinary glass capillaries, while solids can be analyzed as powders packed in capillaries or as potassium...
The monochromatic laser source, typically using visible or near-infrared radiation, generates a highly focused beam of light. This light interacts with the molecules of the sample, scattering some of the light. Liquid and gaseous samples are usually tested in ordinary glass capillaries, while solids can be analyzed as powders packed in capillaries or as potassium...
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The underlying principle of Raman spectroscopy is based on the interaction between light and matter, specifically molecules' inelastic scattering of photons. When a monochromatic beam of light, typically from a laser source, interacts with a sample, most scattered light has the same frequency as the incident light. This is known as Rayleigh scattering.
However, a small fraction of the scattered light exhibits a frequency shift due to the exchange of energy between the incident photons and the...
However, a small fraction of the scattered light exhibits a frequency shift due to the exchange of energy between the incident photons and the...

