Analysis of time-dependent scattering spectra for studying processes associated with microdroplets

Techniques are presented for analysis of time-dependent scattering spectra from single droplets undergoing physical changes. Times of appearance of resonances in experimental spectra are aligned with theoretical resonances, and the size and refractive index of a droplet as functions of time are determined from the minimum errors in alignment between observed and theoretical resonances. The techniques have been applied to time-dependent elastic scattering spectra obtained from single droplets evaporating under quasi-steady conditions and during unsteady growth. The results of quasi-steady evaporation data show that size and refractive index can be determined with relative errors of 1 x 10(-4). The quasi-steady evaporation data of a droplet are used to identify the resonances observed during the unsteady growth of the same droplet, and the size and refractive index at each resonance are calculated from the identity of the resonance.