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An unprecedented (6,8)-connected self-penetrating network based on two distinct zinc clusters
Ya-Qian Lan1, Xin-Long Wang, Shun-Li Li
1Institute of Functional Material Chemistry, Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun 130024, China.
Abstract:
The first (6,8)-connected self-penetrating metal-organic framework has been constructed using an asymmetric neutral ligand based on dinuclear zinc clusters, as six-connected nodes, and trinuclear zinc clusters as eight-connected nodes, representing the highest-connected binodal network topology presently known for self-penetrating systems.
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