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Localized Pd overgrowth on cubic Pt nanocrystals for enhanced electrocatalytic oxidation of formic acid
Hyunjoo Lee1, Susan E Habas, Gabor A Somorjai
1Department of Chemical Engineering, Yonsei University, Seoul, South Korea.
Journal of the American Chemical Society
|March 28, 2008
Abstract:
Binary Pt/Pd nanoparticles were synthesized by localized overgrowth of Pd on cubic Pt seeds for the investigation of electrocatalytic formic acid oxidation. The binary particles exhibited much less self-poisoning and a lower activation energy relative to Pt nanocubes, consistent with the single crystal study.
