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Updated: Jul 6, 2026

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Isolation and structure determination of the cembranoid eunicin from a new genus of octocoral, Pseudoplexaura
William R Sponholtz1, Michelle A Bianco, Gordon W Gribble
1Department of Science, Cushing Academy, Ashburnham, MA 01430, USA.
Abstract:
The known cembranoid diterpene eunicin (1) was isolated from a new genus of octocoral, Pseudoplexaura, collected in the Caribbean. The complete assignment of the 13C and 1H NMR spectra, including differentiation of pro-R and pro-S hydrogens and elucidation of all J values, was accomplished with the aid of TOCSY, HSQC, and HMBC data, and a consideration of three low-energy conformations using SYBYL.
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