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Tuning the nucleophilicity in cyclopropenylidenes

Wolfgang W Schoeller1, Guido D Frey, Guy Bertrand

  • 1Fakultät für Chemie der Universität, Universität Bielefeld, Bielefeld, Germany. wolfgang.schoeller@ucr.edu

Chemistry (Weinheim an Der Bergstrasse, Germany)
|April 12, 2008
PubMed
Summary

Cyclopropenylidenes, aromatic pi systems with carbene centers, exhibit significant singlet-triplet energy gaps influenced by substituents. These compounds can be stabilized to prevent dimerization and tuned for enhanced nucleophilicity.

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