![Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F51444.jpg&w=3840&q=50)
Lithium-palladium complex supported by phosphonatophosphine and chloride ligands
Adel Hamada1, Pierre Braunstein
1Laboratoire de Chimie de Coordination, Institut de Chimie (UMR 7177 CNRS), Université Louis Pasteur, 4 rue Blaise Pascal, F-67070 Strasbourg Cédex, France.
Inorganic Chemistry
|April 18, 2008
Abstract:
The reaction of the phosphonatophosphine ligand Ph2PCH(SiMe3)P(O)(OEt)2 with [PdCl2(COD)] in the presence of LiCl afforded the neutral, mixed-metal complex [LiPd2CI5{mu-Ph2PCH2P(O)(OEt)2}2] in which the Li(+) cation is tetrahedrally coordinated by the PO bonds and two Pd-bound Cl atoms.
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