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Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
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Beyond Aresta's complex: Ni- and Pd-catalyzed organozinc coupling with CO2

Charles S Yeung1, Vy M Dong

  • 1Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Canada M5S 3H6.

Journal of the American Chemical Society
|May 31, 2008
PubMed
Summary

Organozinc reagents can now react with carbon dioxide (CO2) under mild conditions, thanks to new nickel and palladium catalysts. This breakthrough expands the utility of organometallic reagents in organic synthesis.

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