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Updated: Jul 4, 2026

Molecular Entanglement and Electrospinnability of Biopolymers
Published on: September 3, 2014
Stripe formation in an immiscible polymer blend under electric and shear-flow fields
Yang-Ho Na1, Tetsunori Shibuya, Seiji Ujiie
1Department of Applied Physics, Graduate School of Engineering, Hokkaido University, Sapporo 060-8628, Japan.
Abstract:
We found a stripe formation in an emulsion of a liquid crystalline polymer (LCP) and a machine oil (OIL) in electric and shear fields. Through the simultaneous measurement with a confocal scanning laser microscope and a rheometer, it was clearly shown that the formation of stripes, which are periodically arrayed, leads to the increase of the shear stress. The droplets, which are one component of the emulsion, start to be connected at low electric fields and then change into the stripes with the increase of electric field. Finally, a three-dimensional network is formed at high electric fields. The period and fluctuation of the stripe structure were also investigated in detail.

