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Chemo-enzymatic Synthesis of N-glycans for Array Development and HIV Antibody Profiling
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Expeditive synthesis of glycodendrimer scaffolds based on versatile TRIS and mannoside derivatives
Yoann M Chabre1, Christiane Contino-Pépin, Virginie Placide
1Department of Chemistry, Université du Québec à Montréal, P.O. Box 8888, Succ. Centre-Ville Montréal, Québec, Canada H3C 3P8.
The Journal of Organic Chemistry
|June 25, 2008
Abstract:
A new family of glycodendrimer scaffolds containing 12 and 18 peripheral alpha-d-mannopyranosidic units has been synthesized by Cu(I)-catalyzed [1,3]-dipolar cycloadditions using sulfurated dendritic scaffolds bearing alkyne functionalities and novel TRIS derivatives.
