Silanol-based pincer Pt(II) complexes: synthesis, structure, and unusual reactivity

Edward E Korshin1, Gregory Leitus, Linda J W Shimon

  • 1Department of Organic Chemistry and Unit of Chemical Research Support, Weizmann Institute of Science, 76100 Rehovot, Israel. david.milstein@weizmann.ac.il

Inorganic Chemistry
|July 22, 2008
PubMed
Summary

Researchers explored platinum(II) silanol complexes, observing unusual reactivity and potential silanone intermediates. While stable silanones weren't isolated, novel binuclear complexes and silanolate platinum(II)-hydride species were formed, revealing complex reaction pathways.

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