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Updated: Jul 2, 2026

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
Published on: March 24, 2018
X-Shaped polyphilics: liquid crystal honeycombs with single-molecule walls
Robert Kieffer1, Marko Prehm, Benjamin Glettner
1Martin-Luther-University Halle-Wittenberg, Institute of Chemistry, Organic Chemistry, Kurt-Mothes Strasse 2, Halle, Germany.
Abstract:
X-Shaped ternary five-block molecules, composed of a rigid p-terphenyl core, two terminal glycerol groups and two flexible n-alkyl or semiperfluorinated chains fixed laterally to opposite sides of the terphenyl moiety, form liquid crystalline phases built up of honeycomb-like arrays of polygonal cylinders, where the rod-like aromatic cores form cylinder walls with a thickness equal to the width of a single molecule.
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