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Updated: Jul 2, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Phosphite-derivatized ruthenium-carbohydrate complexes in the catalytic hydration of nitriles. short communication
Shaheen M Ashraf1,2, Isabella Berger1, Alexey A Nazarov1,3
1University of Vienna, Institute of Inorganic Chemistry, Waehringer Strasse 42, A-1090 Vienna, (phone: +43-1-4277-52609; fax: +43-1-4277-52680).
Abstract:
The synthesis of metal complexes with bioligands is one option to introduce chirally defined ligands to catalysts. Herein, the hydration of nitriles to the corresponding carboxamides by use of ruthenium(II) complexes is described, which were obtained by attaching derivatives of the 3,5,6-bicyclophosphite-alpha-D-glucofuranoside ligand.
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