Remote induction of asymmetry in [13]-macro-dilactone topology by a single stereogenic center
1Department of Chemistry, University of Connecticut, Storrs, CT 06269, USA.
Chemical Communications (Cambridge, England)
|September 2, 2008
Abstract:
Analysis of a series of unsaturated [13]-macro-dilactones showed that the configuration of a single carbon dictates the planar chirality of a macrocycle backbone and in turn remotely switches the facial display of an embedded alkene unit.
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