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Trinuclear rhodium complexes and their relevance for asymmetric hydrogenation

Angelika Preetz1, Wolfgang Baumann, Hans-Joachim Drexler

  • 1Leibniz-Institut für Katalyse e. V. Albert-Einstein-Str. 29a, 18059 Rostock, Germany.

Chemistry, an Asian Journal
|September 4, 2008
PubMed

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The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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Radical substitution reactions can be used to remove functional groups from molecules. The hydrogenolysis of alkyl halides is one such reaction, where the weak Sn–H bond in tributyltin hydride reacts with alkyl halides to form alkanes. Here, the reagent Bu3SnH yields tributyltin halide as a byproduct.
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